The Hei and HeH Photoelectron Spectra of [ Fe * ?
نویسندگان
چکیده
By means of UV photoelectron spectroscopy (UPS) the electronic structures of [Fe^3.C3H5(CO)3X], [Fe^3-(2-CH3C3H4)(CO)3X] (X = Cl, Br, I) and [Co(C3H5)(CO)3] have been studied. Detailed assignments are possible and surprisingly low ionization energies (as low as 8.19 eV) are found for iodine lone pair type Orbitals. From the spectra a large difference in n backbonding is found between the cobalt and iron complexes.
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